What is Le Chatelier's Principle?
- If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to counteract the change.
Soo basically, Le Chatelier's Principle says that if you change the condition of an equation's equillibrium....the equation will compensate by shifting to the left or to the right to maintain its equillibrium. You can affect a reaction by changing its pressure, temperature, or concentration.
Changes in Concentration:
- Using Le Chatelier's Principle, we know that the position of equilibrium will move to counteract the changes made in concentration.
If the concentration of A is increased, the position of equilibrium will move to the right so the concentration of A decreases again. But if the concentration of A is decreased, then the equilibrium shifts to the left to replace what it has lost.
- For this type of reaction, you need to know whether the heat is being absorbed or let out. If the heat of reaction is a part of the product and less than zero, then the reaction is exothermic. If the heat of reaction is a part of the reactants and greater than zero, then the reaction is endothermic. When temperature is increased or decreased, the equilibrium will shift to whichever side has less heat so it may balance out the reaction.
Changes in Pressure:
- In this reaction, when you increase pressure the equilibrium will shift towards the side with the least amount of molecules. However, a decrease in pressure results in a shift towards the side with more molecules in order to increase the pressure overall.
C(s) + H2O(g) <--> CO(g) + H2(g)
If you increase the pressure, the equilibrium will shift towards the left. There is one gas particle on the left but there are two on the right....this means that when you increase pressure, the equilibrium will shift towards the side with less gas particles (the left).